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Alkanes questions

Chemistry · 3rd secondary (languages) · Organic Chemistry

Question bank for the lesson "Alkanes" with 60 questions. Pick a set and start: you see at once whether your answer is right and read the explanation. Free, no sign-up.

Lesson questions

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Multiple choice questions

  1. What is the IUPAC name of the opposite compound?

    Figure of question 1
    1. A 1-methylbutane.
    2. B 1,3-methylpropane.
    3. C 1,3-dimethylpropane.
    4. D normal pentane.
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  2. From the opposite structural formulas:
    Which of the following represents normal butane?

    Figure of question 2
    1. A (2) only.
    2. B (3) only.
    3. C (1) , (2).
    4. D (2) , (3).
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  3. Any two successive members of the alkane series ..........

    1. A differ in the general formula.
    2. B differ in the molar mass.
    3. C have the same density.
    4. D have the same chemical formula.
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  4. What is the molecular formula of the alkane whose molar mass is greater than the molar mass of another compound in the same series by 56?
    [C = 12 , H = 1]

    1. A C₄H₁₀
    2. B C₅H₁₀
    3. C C₆H₁₄
    4. D C₆H₁₂
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  5. The members of one homologous series have the same ..........

    1. A chemical formula.
    2. B general formula.
    3. C physical properties.
    4. D structural formula.
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  6. The members of the alkane series have all of the following in common, except ..........

    1. A that they are isomers of each other.
    2. B that they have similar chemical properties.
    3. C that they follow a general molecular formula.
    4. D that the difference in molar mass between any two successive compounds is 14
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  7. Isomerism in alkanes starts to appear with the compound ..........

    1. A methane.
    2. B ethane.
    3. C propane.
    4. D butane.
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  8. Butane differs from methylpropane in ..........

    1. A the homologous series.
    2. B the general formula.
    3. C the molecular formula.
    4. D the structural formula.
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  9. What is the general formula of alkyl halides?

    1. A CₙH₂ₙ₊₁X
    2. B CₙH₂ₙ₊₂X
    3. C CₙHₙ₊₁X
    4. D CₙH₂ₙX
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  10. Which of the following is the IUPAC name of the compound that contains (4) methyl groups?

    1. A normal hexane.
    2. B 2,3-dimethylbutane.
    3. C 2-methylpentane.
    4. D tetramethylbutane.
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  11. What is the number of methyl groups in the branched alkane whose molar mass is (58 g/mol)?
    [C = 12 , H = 1]

    1. A 1
    2. B 2
    3. C 3
    4. D 4
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  12. What is the number of methylene groups in the compound 3-ethylpentane?

    1. A 2
    2. B 3
    3. C 4
    4. D 5
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  13. What is the IUPAC name of the opposite compound?

    Figure of question 13
    1. A pentane.
    2. B 3-methylbutane.
    3. C 2-methylbutane.
    4. D butane.
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  14. The opposite figure represents the carbon skeleton of a hydrocarbon.
    What is the IUPAC name of this compound?

    Figure of question 14
    1. A 2,4-diethyl-3,6-dimethylheptane.
    2. B 2,5-dimethyl-4,6-diethylheptane.
    3. C 5-ethyl-3,4,7-trimethyloctane.
    4. D 4-ethyl-2,5,6-trimethyloctane.
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  15. What is the IUPAC name of the opposite compound?

    Figure of question 15
    1. A 2,4-dimethylhexane.
    2. B 3,5-dimethylhexane.
    3. C 2-methyl-4-ethylpentane.
    4. D 2-ethyl-4-methylpentane.
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  16. What is the IUPAC name of the opposite compound?
    CH₃(CH₂)₂CH(CH₃)CH(CH₃)₂

    1. A 2,3-dimethyloctane.
    2. B 2,3-dimethylhexane.
    3. C 4,5-dimethyloctane.
    4. D 4,5-dimethylhexane.
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  17. The compound 2,2,3-trimethylhexane is represented by the chemical formula ..........

    1. A CH₃C(CH₃)₂CH₂CH₂CH(CH₃)₂
    2. B CH₃C(CH₃)₂CH₂CH(CH₃)CH₂CH₃
    3. C CH₃C(CH₃)₂CH(CH₃)CH₂CH₂CH₃
    4. D CH₃C(CH₃)₂CH₂C(CH₃)₂CH₃
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  18. From the opposite table:
    (1) 2-methylbutane
    (2) normal octane
    (3) 2,2,3-trimethylbutane
    (4) 2,2-dimethylpropane
    Which two compounds have the same molar mass?

    1. A (1) , (2).
    2. B (1) , (4).
    3. C (2) , (3).
    4. D (3) , (4).
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  19. Here are four structural formulas:
    Which two formulas are named 2,2,4-trimethylpentane?

    Figure of question 19
    1. A (1) , (3).
    2. B (1) , (4).
    3. C (2) , (3).
    4. D (2) , (4).
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  20. Which of the following is the IUPAC name of the compound that contains no methylene groups?

    1. A normal hexane.
    2. B 2,3-dimethylbutane.
    3. C 2-methylpentane.
    4. D 2,2-dimethylbutane.
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  21. An alkane contains 5 methyl groups and 2 methylene groups.
    What is the IUPAC name of this compound?

    1. A 2,3,4-trimethylhexane.
    2. B 2,2,4-trimethylhexane.
    3. C 2,2,3,4-tetramethylpentane.
    4. D 2,3,3,4-tetramethylpentane.
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  22. A paraffin compound has (16) sigma bonds in its molecule.
    What is the IUPAC name of an isomer of it that contains no methylene groups?

    1. A 2-methylpropane.
    2. B dimethylpropane.
    3. C ethane.
    4. D 2,3-dimethylbutane.
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  23. What is the IUPAC name of the opposite compound?
    CH₃–CH₂–CH₂–CH₂–CH₂Cl

    1. A pentyl chloride.
    2. B hexane.
    3. C 5-chloropentane.
    4. D 1-chloropentane.
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  24. What is the IUPAC name of the opposite compound?

    Figure of question 24
    1. A 2-methyl-2-chlorobutane.
    2. B 2-chloro-2-methylbutane.
    3. C 3-methyl-3-chlorobutane.
    4. D 3-chloro-3-methylbutane.
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  25. What is the IUPAC name of the opposite compound?

    Figure of question 25
    1. A 3-bromo-2-methylpentane.
    2. B 2-methyl-3-bromopentane.
    3. C 3-bromo-2-methylhexane.
    4. D 2-methyl-3-bromohexane.
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  26. What is the IUPAC name of the opposite compound?

    Figure of question 26
    1. A 2-chloro-2-fluorobutane.
    2. B 2-fluoro-3-chlorobutane.
    3. C 3-fluoro-2-chlorobutane.
    4. D 2-chloro-3-fluorobutane.
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  27. What is the IUPAC name of the opposite compound?

    Figure of question 27
    1. A 1,2-dichloro-1,2-dimethylpropane.
    2. B 2,3-dichloro-2,3-dimethylpropane.
    3. C 2,3-dichloro-2-methylbutane.
    4. D 2,3-dichloro-3-methylbutane.
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  28. What is the IUPAC name of the opposite compound?

    Figure of question 28
    1. A 3,4-dichloro-2-fluorohexane.
    2. B 3,4-dichloro-5-fluorohexane.
    3. C 2-fluoro-3,4-dichlorohexane.
    4. D 2,3-dichloro-2-fluoro-1-methylpentane.
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  29. What is the IUPAC name of the opposite compound?

    Figure of question 29
    1. A 2,3-dibromo-2-fluoropropane.
    2. B 2-fluoro-2,3-dibromopropane.
    3. C 1,2-dibromo-2-fluoropropane.
    4. D 2-fluoro-1,2-dibromopropane.
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  30. What is the structural formula of the compound 5-chloro-2,2-dimethylhexane?

    Figure of question 30
    1. A A
    2. B B
    3. C C
    4. D D
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  31. What is the number of isomers of the molecular formula C₃H₆Cl₂?

    1. A 2
    2. B 3
    3. C 4
    4. D 5
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  32. All of the following are correct names according to the IUPAC system, except ..........

    1. A 3-chloro-2,2-dimethylbutane.
    2. B 2,3-dimethylpentane.
    3. C 2-chloro-1,1-dimethylpropane.
    4. D 2-bromo-2-chlorohexane.
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  33. Which of the following is the correct IUPAC name of an organic compound?

    1. A 2-chloro-3-bromopentane.
    2. B 3-bromo-2-chloropentane.
    3. C 4-bromo-2-chloropentane.
    4. D 2-chloro-4-bromopentane.
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  34. What is the number of isomers of the chemical formula C₂H₃F₃?

    1. A 1
    2. B 2
    3. C 3
    4. D 4
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  35. Isomers of saturated hydrocarbons are formed when ..........

    1. A the number of carbon atoms is changed.
    2. B the number of hydrogen atoms is changed.
    3. C branches are formed in the chain of carbon atoms.
    4. D double bonds are formed.
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  36. The compound 2,2-dimethylbutane is an isomer of the compound ..........

    1. A 2-methylbutane.
    2. B 2,2-dimethylpentane.
    3. C 2-methylpentane.
    4. D 2,2-dimethylpropane.
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  37. What is the number of isomers of the molecular formula C₂H₃Cl₂Br?

    1. A 2
    2. B 3
    3. C 4
    4. D 5
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  38. What is the number of isomers of the molecular formula C₃H₅Br₃?

    1. A 2
    2. B 3
    3. C 4
    4. D 5
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  39. What is the number of possible isomers when a hydrogen atom in a molecule of 2,2-dimethylbutane is replaced by one chlorine atom (without changing the arrangement of the carbon skeleton)?

    1. A 2
    2. B 3
    3. C 4
    4. D 5
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  40. What is the number of isomers of the molecular formula C₆H₁₄?

    1. A 4
    2. B 5
    3. C 6
    4. D 7
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  41. A hydrocarbon has the molecular formula C₆H₁₄
    What is the number of its isomers that contain 3 methyl groups, and what is the number of methylene groups in each of these isomers?

    1. A 2 isomers / 3 methylene groups.
    2. B 2 isomers / 2 methylene groups.
    3. C 3 isomers / 2 methylene groups.
    4. D 3 isomers / 3 methylene groups.
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Essay questions

  1. The compound C₇H₁₆ belongs to one of the homologous series:
    (1) What is the molecular formula of the first member of this series?
    (2) What is the type of bonds between the atoms of this compound?

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  2. Draw the possible isomers of the molecular formula C₄H₉Cl

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  3. Explain: the compound CH₃CHBrCH₂CH(CH₃)CH₃ is named 2-bromo-4-methylpentane, not 2-methyl-4-bromopentane.

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  4. What is the name and the molecular formula of the alkane - unbranched - of which the compound 3-ethyl-2-methylpentane is one of the isomers?

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  5. A saturated, non-cyclic aliphatic hydrocarbon is made of 14 atoms:
    (1) What is the number of carbon atoms and hydrogen atoms in it?
    (2) What are its possible structural formulas? Name each of them.

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  6. The molecular formula C₅H₁₂ represents three isomers.
    Draw the structural formula of each of them, and name them according to the IUPAC system.

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  7. Among the isomers of hexane are two compounds whose longest continuous chain is made of 4 carbon atoms.
    Draw the structural formula of these two isomers, and name them according to the IUPAC system.

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  8. Three alkanes differ in their number of isomers:
    Alkane (X): 35 isomers. Alkane (Y): 18 isomers. Alkane (Z): 75 isomers.
    Choose for each of these alkanes its suitable name from the following, and explain.
    Octane. Decane. Nonane.

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  9. Write the IUPAC name of each of the following two compounds:

    Figure of question 9Solve this question →
  10. Write the IUPAC name of each of the following two compounds, in which each point of the skeleton represents a carbon atom:

    Figure of question 10Solve this question →
  11. Two alkane isomers have a molar mass of 58 g/mol. Draw the structural formula of each of them, and write the IUPAC name of each.
    [C = 12 , H = 1]

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  12. Draw the structural formula and write the molecular formula of each of:
    (1) 3-chloro-2-methylpentane.
    (2) an alkane made of 5 carbon atoms that has no methylene groups.

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  13. Draw the structural formula of each of the following two compounds, then write the correct name of each according to the IUPAC system:
    (1) 4-bromobutane.
    (2) 3-methylbutane.

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From past exams

  1. An alkane has the molecular formula C₆H₁₄ and contains four methyl groups and no methylene groups. (Sample exam 2026)
    Which of the following is the IUPAC name of this compound?

    1. A 2,2-dimethylbutane.
    2. B 3,3-dimethylbutane.
    3. C 2,3-dimethylbutane.
    4. D 1,4-dimethylbutane.
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  2. From the names of the following compounds: (2nd session 2024)
    (A): 2-ethyl-3-methylbutane.
    (B): 3,4,4,5-tetramethyloctane.
    Which of the following statements is correct?

    1. A Name (A) is correct, (B) is wrong.
    2. B Name (A) is wrong, (B) is correct.
    3. C Name (A) is wrong, (B) is wrong.
    4. D Name (A) is correct, (B) is correct.
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  3. In the formula: (Trial exam / June 2021)
    After rewriting its correct structural formula without changing the molecular formula, it represents a(n) .......... compound.

    Figure of question 3
    1. A open-chain aliphatic
    2. B unsaturated
    3. C alkene
    4. D branched alkene
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  4. One of the following compounds has only three isomers .......... (Trial exam / May 2021)

    1. A propane.
    2. B pentane.
    3. C hexane.
    4. D butane.
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  5. The compounds that can be similar in physical state and chemical properties are .......... (2nd session 2021)

    1. A C₁₈H₃₈ , C₈H₁₈
    2. B C₁₈H₃₈ , C₂₀H₄₂
    3. C C₈H₁₆ , C₃H₄
    4. D C₁₆H₃₂ , C₃H₆
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  6. The opposite compound: (CH₃)₂C(C₆H₅)CH₂CH(CH₃)₂ (1st session 2024)
    Which of the following choices is the name of the compound according to the IUPAC system?

    1. A 2,4-dimethyl-4-phenylpentane.
    2. B 1,1,3,3-tetramethyl-1-phenylpropane.
    3. C 2,4-dimethyl-2-phenylpentane.
    4. D 2,4,4-trimethyldecane.
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